open that file in PS, resize it to 1024*1024, choose a suitable font and lay the new letters over the old ones (using layers, I would use a different layer for each letter). when finished Hide the original layer.
save as png (and keep the .PSD file with all the layers in case the letters don't exactly match.)
save as png (and keep the .PSD file with all the layers in case the letters don't exactly match.)

